Small Organic Peroxy Radicals – Table 7

Table 7. Reaction 7 C2H5O2 + NO

Reference Total press.
(Torr)
k(298 K)a Aa E/R (K) Temp range(K) Method
Adachi and Basco (1979) 40-80 (Ar) 2.65 298 FP-UV
Plumb et al. (1982) 5 (He) 8.9 298 DF-MS
Sehested et al. (1993) 760 (SF6) 8.5 298 PR-UV
Daële et al. (1995) 1 (He) 8.2 298 DF-MS
Eberhard and Howard (1996) 2-6 (He) 9.3 2.6 -380 201-403 DF-CI
Maricq and Szente (1996) 100 (N2) 9.4 3.1 -330 220-355 LP-UV/IR
Ranschaert et al. (2000) 100 Torr (N2) 10.1 3.8 290 213-299 TFT-CI
Recommendedb 8.9±0.9 2.7 -355±50

a) Units of 10-12 cm3molecule-1s-1; b) ignoring the value of Adachi and Basco, errors are 2σ.