Figure 6 Reaction 6 C2H5O2 + HO2
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Table 6. Reaction 6 C2H5O2 + HO2
Reference | s (C2H5O2) 240nma |
s (HO2) 210nma |
k(298K)b 10-12 |
Ab 10-12 |
E/R (K) | Temp range(K) | Method |
---|---|---|---|---|---|---|---|
Cattell et al. (1986) | 4.5 | 4.22 | 6.3 | 295 | MMS | ||
Dagaut et al. (1988) | 4.15 | 3.65 | 7.3 (7.7)c |
0.56 | -650 | 248-380 | FP |
Fenter et al. (1993) | 4.89 | 4.80 | 11.0 (10.0)c |
0.16 | -1260 | 248-480 | FP |
Maricq and Szente (1994) | 4.60 | 3.85 | 7.2 | 0.69 | -702 | 210-363 | FP |
Recommendedd | 4.52 | 4.01 | 7.8±2.6e | 0.74 | -700 |
a) Units of 10-18 cm2molecule-1; b) units of 10-12 cm3molecule-1s-1; c) Reanalyzed with recommended σ values; d) Based on Dagaut et al. and Maricq and Szente; e) errors are 2σ.